Literature DB >> 10956509

Dynamic hemicarcerands and hemicarceplexes.

S Ro1, S J Rowan, A R Pease, D J Cram, J F Stoddart.   

Abstract

The reversible nature of the imine bond formation in CDCl(3) solution has been exploited to exchange substituted for unsubstituted m-phenylenediamine (MPD) units in hemicarcerand octaimines. Moreover, acid-catalyzed imine exchange has been shown to provide a novel mechanism whereby ferrocene (Fc) can be released as an entrapped guest from the hemicarceplex C(2)B(4)&crcldt;Fc dissolved in CDCl(3) to give the hemicarcerand C(2)B(4) when excess of both MPD and trifluoroacetic acid are present.

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Year:  2000        PMID: 10956509     DOI: 10.1021/ol005962p

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  10 in total

1.  Supramolecular templating in thermodynamically controlled synthesis.

Authors:  Ricardo L E Furlan; Sijbren Otto; Jeremy K M Sanders
Journal:  Proc Natl Acad Sci U S A       Date:  2002-03-05       Impact factor: 11.205

2.  Molecular shape sorting using molecular organic cages.

Authors:  Tamoghna Mitra; Kim E Jelfs; Marc Schmidtmann; Adham Ahmed; Samantha Y Chong; Dave J Adams; Andrew I Cooper
Journal:  Nat Chem       Date:  2013-01-20       Impact factor: 24.427

Review 3.  Purely Covalent Molecular Cages and Containers for Guest Encapsulation.

Authors:  Giovanni Montà-González; Félix Sancenón; Ramón Martínez-Máñez; Vicente Martí-Centelles
Journal:  Chem Rev       Date:  2022-07-22       Impact factor: 72.087

4.  Combinatorial synthesis of chemical building blocks 1. Azomethines.

Authors:  Sergey V Ryabukhin; Dmitriy M Panov; Andrey S Plaskon; Alexander Chuprina; Sergey E Pipko; Andrey A Tolmachev; Alexander N Shivanyuk
Journal:  Mol Divers       Date:  2012-10-30       Impact factor: 2.943

5.  Template-directed self-assembly of dynamic covalent capsules with polar interiors.

Authors:  Albano Galán; Eduardo C Escudero-Adán; Pablo Ballester
Journal:  Chem Sci       Date:  2017-09-26       Impact factor: 9.825

6.  Transformation of a [4+6] Salicylbisimine Cage to Chemically Robust Amide Cages.

Authors:  Avinash S Bhat; Sven M Elbert; Wen-Shan Zhang; Frank Rominger; Michael Dieckmann; Rasmus R Schröder; Michael Mastalerz
Journal:  Angew Chem Int Ed Engl       Date:  2019-05-17       Impact factor: 15.336

7.  Host-Guest Chemistry of Truncated Tetrahedral Imine Cages with Ammonium Ions.

Authors:  Jochen C Lauer; Ziwei Pang; Paul Janßen; Frank Rominger; Tobias Kirschbaum; Marcus Elstner; Michael Mastalerz
Journal:  ChemistryOpen       Date:  2020-02-03       Impact factor: 2.911

8.  Dissipative Formation of Covalent Basket Cages.

Authors:  Vageesha W Liyana Gunawardana; Tyler J Finnegan; Carson E Ward; Curtis E Moore; Jovica D Badjić
Journal:  Angew Chem Int Ed Engl       Date:  2022-07-11       Impact factor: 16.823

9.  Probing the Dynamics of the Imine-Based Pentafoil Knot and Pentameric Circular Helicate Assembly.

Authors:  Jean-François Ayme; Jonathon E Beves; Christopher J Campbell; David A Leigh
Journal:  J Am Chem Soc       Date:  2019-02-14       Impact factor: 15.419

10.  Examination of the Dynamic Covalent Chemistry of [2 + 3]-Imine Cages.

Authors:  Tobias H G Schick; Frank Rominger; Michael Mastalerz
Journal:  J Org Chem       Date:  2020-10-09       Impact factor: 4.354

  10 in total

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