Literature DB >> 10944284

trans-Bis(diethanolamine)bis(isothiocyanato)nickel(II)

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Abstract

In the neutral title complex, trans-bis(2,2'-iminodiethanol-N, O)bis(isothiocyanato)nickel(II), [Ni(NCS)(2)(C(4)H(11)NO(2))(2)], the isothiocyanate ions and the diethanolamine molecules act as monodentate and bidentate ligands, respectively. The Ni(II) ion exhibits a distorted octahedral configuration with crystallographically imposed inversion symmetry and N(NCS)-Ni-N(amine) and N(NCS)-Ni-O(amine) bond angles of 88.78 (10) and 89.44 (10) degrees, respectively. The Ni-N bond distances are in the range 2.069 (3)-2.096 (2) A. The molecules are linked by hydrogen bonds to form a three-dimensional infinite lattice.

Entities:  

Year:  2000        PMID: 10944284     DOI: 10.1107/s0108270100007289

Source DB:  PubMed          Journal:  Acta Crystallogr C        ISSN: 0108-2701            Impact factor:   1.172


  2 in total

1.  [N-(8-Quinolylmeth-yl)imino-diethanol-κN,N',O,O']bis-(thio-cyanato-κN)nickel(II) monohydrate.

Authors:  Rui-Feng Song; Yu-Hong Wang
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2007-12-06

2.  Crystal structure of trans-bis-(di-ethano-lamine-κ(3) O,N,O')manganese(II) bis-(3-amino-benzoate).

Authors:  Aziz B Ibragimov; Bakhtiyar S Zakirov; Jamshid M Ashurov
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2016-03-15
  2 in total

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