High-Resolution Fourier Spectrometry of the (14)N(+)(2) Ion.

Rotational analyses of the B(2)Sigma(+)(u) --> X(2)Sigma(+)(g) system of the (14)N(+)(2) molecule have been extended to include the vibrational levels up to v' = 4. Spectral data from 20 bands obtained from high-resolution Fourier transform spectrometry of a hollow-cathode and a Pointolite lamp were included in the analysis. A global deperturbation yielded molecular parameters of the highly perturbed B(2)Sigma state and interaction parameters A(2)Pi(u) approximately B(2)Sigma(u) with a standard deviation of 0.011 cm(-1). Rotational term values of the B(2)Sigma(+) state were also determined. New perturbations in the B(2)Sigma(+) (v = 0) level have been observed at N approximately 85 and N approximately 96. Copyright 2000 Academic Press.