Literature DB >> 10930288

Dynamic kinetic resolution of allylic alcohols mediated by ruthenium- and lipase-based catalysts.

D Lee1, E A Huh, M J Kim, H M Jung, J H Koh, J Park.   

Abstract

An enzyme-metal combo reaction has been developed for the dynamic kinetic resolution of allylic alcohols in which racemic substrates are transformed by a lipase and a ruthenium complex in the presence of an acyl donor to allylic acetates of high optical purity in over 80% yield.

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Year:  2000        PMID： 10930288     DOI： 10.1021/ol006159y

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  3 in total

1.  Direct Synthesis of Allyl Amines with 2-Nitrosulfonamide Derivatives via the Tsuji-Trost Reaction.

Authors:  Corentin Bon; Paola B Arimondo; Ludovic Halby
Journal:  ChemistryOpen       Date:  2021-08-15       Impact factor: 2.630

2.  One-pot synthesis of enantiopure syn-1,3-diacetates from racemic syn/anti mixtures of 1,3-diols by dynamic kinetic asymmetric transformation.

Authors:  Michaela Edin; Johannes Steinreiber; Jan-E Bäckvall
Journal:  Proc Natl Acad Sci U S A       Date:  2004-04-06       Impact factor: 11.205

Review 3.  Chemoenzymatic dynamic kinetic resolution: a powerful tool for the preparation of enantiomerically pure alcohols and amines.

Authors:  Oscar Verho; Jan-E Bäckvall
Journal:  J Am Chem Soc       Date:  2015-03-19       Impact factor: 15.419
  3 in total

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