Literature DB >> 10891241

Platinum-catalyzed diboration using a commercially available catalyst: diboration of aldimines to alpha-aminoboronate esters

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Abstract

Commercially available Pt(cod)Cl(2) catalyzes the diboration of alkenes, alkynes, and aldimines using bis(catecholato)diboron (cod = 1,5-cyclooctadiene). Catalyzed aldimine diboration provides the first direct route to alpha-aminoboronate esters. The diboration product from N-benzylidene-2,6-dimethylaniline is structurally characterized.

Entities:  

Year:  2000        PMID： 10891241     DOI： 10.1021/ol006008v

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  8 in total

1.  Ni(0)-catalyzed 1,4-selective diboration of conjugated dienes.

Authors:  Robert J Ely; James P Morken
Journal:  Org Lett       Date:  2010-10-01       Impact factor: 6.005

2.  Pt-catalyzed enantioselective diboration of terminal alkenes with B2(pin)2.

Authors:  Laura T Kliman; Scott N Mlynarski; James P Morken
Journal:  J Am Chem Soc       Date:  2009-09-23       Impact factor: 15.419

3.  Scope and mechanism of the Pt-catalyzed enantioselective diboration of monosubstituted alkenes.

Authors:  John R Coombs; Fredrik Haeffner; Laura T Kliman; James P Morken
Journal:  J Am Chem Soc       Date:  2013-07-18       Impact factor: 15.419

4.  Catalytic enantioselective one-pot aminoborylation of aldehydes: a strategy for construction of nonracemic α-amino boronates.

Authors:  Kai Hong; James P Morken
Journal:  J Am Chem Soc       Date:  2013-06-13       Impact factor: 15.419

5.  Recent Advances in the C-H-Functionalization of the Distal Positions in Pyridines and Quinolines.

Authors:  David E Stephens; Oleg V Larionov
Journal:  Tetrahedron       Date:  2015-08-19       Impact factor: 2.457

6.  Facile formation of β-hydroxyboronate esters by a Cu-catalyzed diboration/Matteson homologation sequence.

Authors:  Cameron M Moore; Casey R Medina; Peter C Cannamela; Melissa L McIntosh; Carl J Ferber; Andrew J Roering; Timothy B Clark
Journal:  Org Lett       Date:  2014-11-20       Impact factor: 6.005

7.  Platinum Cyclooctadiene Complexes with Activity against Gram-positive Bacteria.

Authors:  Angelo Frei; Soumya Ramu; Gabrielle J Lowe; Hue Dinh; Lucie Semenec; Alysha G Elliott; Johannes Zuegg; Anke Deckers; Nicole Jung; Stefan Bräse; Amy K Cain; Mark A T Blaskovich
Journal:  ChemMedChem       Date:  2021-07-08       Impact factor: 3.540

8.  Stereoselective formation of trisubstituted vinyl boronate esters by the acid-mediated elimination of α-hydroxyboronate esters.

Authors:  Weiye Guan; Alicia K Michael; Melissa L McIntosh; Liza Koren-Selfridge; John P Scott; Timothy B Clark
Journal:  J Org Chem       Date:  2014-07-14       Impact factor: 4.354
  8 in total

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