Literature DB >> 10825996

A method for constructing the C44-C51 side chain of altohyrtin C.

G R Ott1, C H Heathcock.   

Abstract

[formula: see text] A method to construct the C44-C51 side chain of altohyrtin C has been developed and applied to a model aldehyde derived from D-glucose. The approach relies on a Wittig reaction to couple the side chain to an aldehyde and utilizes an allylic diazene rearrangement to place the C45 double bond in the correct position.

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Year:  1999        PMID： 10825996     DOI： 10.1021/ol990281j

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  3 in total

1.  N-isopropylidene-N'-2-nitrobenzenesulfonyl hydrazine, a reagent for reduction of alcohols via the corresponding monoalkyl diazenes.

Authors:  Mohammad Movassaghi; Omar K Ahmad
Journal:  J Org Chem       Date:  2007-02-03       Impact factor: 4.354

2.  The catalytic asymmetric Diels-Alder reactions and post-cycloaddition reductive transpositions of 1-hydrazinodienes.

Authors:  Hao Xie; Glenn M Sammis; Eric M Flamme; Christina M Kraml; Erik J Sorensen
Journal:  Chemistry       Date:  2011-09-05       Impact factor: 5.236

3.  Preparation of n-Isopropylidene-n'-2-Nitrobenzenesulfonyl Hydrazine (IPNBSH) and Its Use in Palladium-catalyzed Synthesis of Monoalkyl Diazenes. Synthesis of 9-Allylanthracene.

Authors:  Jens Willwacher; Omar K Ahmad; Mohammad Movassaghi; Juliane Keilitz; Mark Lautens
Journal:  Organic Synth       Date:  2011-12-02
  3 in total

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