Literature DB >> 10822590

A novel chromium(0)-promoted four-component cycloaddition reaction.

J H Rigby1, C R Heap, N C Warshakoon, M J Heeg.   

Abstract

[formula: see text] Reaction of (eta 6-thiepin-1,1-dioxide)tricarbonylchromium(0) with excess terminal alkynes under photoactivation conditions affords novel pentacyclic adducts formally derived from a sequential [6 pi + 2 pi]/[6 pi + 2 pi]/[2 sigma + 2 pi] cycloaddition process.

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Year:  1999        PMID: 10822590     DOI: 10.1021/ol990687w

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  1 in total

1.  Chromium(0)-promoted [6pi + 2pi] cycloadditions of allenes with cycloheptatriene.

Authors:  James H Rigby; Stéphane B Laurent; Zeeshan Kamal; Mary Jane Heeg
Journal:  Org Lett       Date:  2008-12-18       Impact factor: 6.005

  1 in total

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