| Literature DB >> 10822528 |
J D Rainier1, Q Xu.
Abstract
[formula: see text] We have identified an unprecedented anionic condensation, fragmentation, and elimination sequence from the coupling of bicyclo[2.2.1]-heptenones with aldehydes. This reaction leads to the stereoselective formation of disubstituted five-membered rings which are present in a wide array of bioactive molecules.Entities:
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Year: 1999 PMID： 10822528 DOI： 10.1021/ol990532o
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005