Literature DB >> 10814443

beta-scission of the N-O bond in alkyl hydroxamate radicals: a fast radical trap.

M Wu1, T P Begley.   

Abstract

[reaction--see text ] The rate of the beta-scission of the N-O bond in the alkyl hydroxamate radical is faster than 2 x 10(8) s(-)(1). This reaction may be useful as a radical trap.

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Year:  2000        PMID： 10814443     DOI： 10.1021/ol991392l

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  2 in total

1.  Aminyl Radical Generation via Tandem Norrish Type I Photocleavage, β-Fragmentation: Independent Generation and Reactivity of the 2'-Deoxyadenosin- N6-yl Radical.

Authors:  Liwei Zheng; Markus Griesser; Derek A Pratt; Marc M Greenberg
Journal:  J Org Chem       Date:  2017-03-20       Impact factor: 4.354

2.  Aromatic thiol-mediated cleavage of N-O bonds enables chemical ubiquitylation of folded proteins.

Authors:  Caroline E Weller; Abhinav Dhall; Feizhi Ding; Edlaine Linares; Samuel D Whedon; Nicholas A Senger; Elizabeth L Tyson; John D Bagert; Xiaosong Li; Ohara Augusto; Champak Chatterjee
Journal:  Nat Commun       Date:  2016-09-29       Impact factor: 14.919
  2 in total

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