Literature DB >> 10814401

Formation of organomagnesium compounds via EtMgBr-mediated radical cyclization of allyl beta-iodoacetals

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Abstract

[reaction: see text] Treatment of allyl beta-iodoacetals with ethylmagnesium bromide in THF provided tetrahydrofuran derivatives in good yields. On the other hand, the reaction in DME provided tetrahydrofuranylmethylmagnesium compounds in good yields.

Entities:  

Year:  2000        PMID： 10814401     DOI： 10.1021/ol991403a

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  3 in total

Review 1.  Advances in transition metal (Pd, Ni, Fe)-catalyzed cross-coupling reactions using alkyl-organometallics as reaction partners.

Authors:  Ranjan Jana; Tejas P Pathak; Matthew S Sigman
Journal:  Chem Rev       Date:  2011-02-14       Impact factor: 60.622

2.  First total synthesis of concavine.

Authors:  François Saint-Dizier; Nigel S Simpkins
Journal:  Chem Sci       Date:  2017-02-24       Impact factor: 9.825

3.  Preparation of Primary and Secondary Dialkylmagnesiums by a Radical I/Mg-Exchange Reaction Using sBu2 Mg in Toluene.

Authors:  Alisa S Sunagatullina; Ferdinand H Lutter; Paul Knochel
Journal:  Angew Chem Int Ed Engl       Date:  2022-02-09       Impact factor: 16.823
  3 in total

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