Literature DB >> 10814322

Mechanism of oxygen transfer in the epoxidation of an olefin by molecular oxygen in the presence of an aldehyde

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Abstract

[reaction: see text] The reaction pathway for peroxide-initiated aldehyde-mediated oxidation of olefins to epoxides by molecular oxygen has been studied. The pathways of reaction via a peroxy acid or an acyl peroxy radical have been differentiated by investigation of the reaction of 4 with oxygen to provide 6 via 8.

Entities:  

Year:  2000        PMID： 10814322     DOI： 10.1021/ol991304x

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  2 in total

1.  Hydroacylation of alpha,beta-unsaturated esters via aerobic C-H activation.

Authors:  Vijay Chudasama; Richard J Fitzmaurice; Stephen Caddick
Journal:  Nat Chem       Date:  2010-06-06       Impact factor: 24.427

2.  Auto-oxidation of Ent-beyer-15-en-19-al isolated from the essential oil of the heartwood of Erythroxylum monogynum Roxb.: formation of 15,16-epoxy-ent-beyeran-19-oic acid and other products.

Authors:  T M Samantha Gome Tennakoon; G M Kamal Bandara Gunaherath; K Tuley Dayananda De Silva; Chayanika Padumadasa; D Siril Abeywickrama Wijesundara; Ajita Mahendra Abeysekera
Journal:  BMC Chem       Date:  2020-03-13
  2 in total

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