Literature DB >> 10742191

Biomimetic modeling of copper oxidase reactivity.

V Mahadevan1, R K Gebbink, T D Stack.   

Abstract

Bioinspired copper-model-complexes that react with O(2) provide an opportunity to probe biological reactivity at a small-molecule level of detail. Biological structural information combined with appropriate ligand design has proven sufficient to create Cu:O(2) complexes capable of external substrate oxidation. Most notable developments during the review period are the bioinspired catalysts capable of aerobic alcohol-oxidation. The extension of this oxidative reactivity to other important organic transformations beyond the scope of the inspiring system completes a modeling paradigm.

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Year:  2000        PMID： 10742191     DOI： 10.1016/s1367-5931(99)00080-0

Source DB:  PubMed          Journal:  Curr Opin Chem Biol        ISSN： 1367-5931            Impact factor:   8.822


  10 in total

Review 1.  Biological inorganic chemistry at the beginning of the 21st century.

Authors:  Harry B Gray
Journal:  Proc Natl Acad Sci U S A       Date:  2003-03-25       Impact factor: 11.205

2.  Design of Heteronuclear Metalloenzymes.

Authors:  A Bhagi-Damodaran; P Hosseinzadeh; E Mirts; J Reed; I D Petrik; Y Lu
Journal:  Methods Enzymol       Date:  2016-07-26       Impact factor: 1.600

Review 3.  High-valent copper in biomimetic and biological oxidations.

Authors:  William Keown; J Brannon Gary; T Daniel P Stack
Journal:  J Biol Inorg Chem       Date:  2016-12-01       Impact factor: 3.358

4.  Synthesis and crystal structure of catena-poly[[tetra-μ-acetato-copper(II)]-μ-6-eth-oxy-N 2,N 4-bis-[2-(pyridin-2-yl)eth-yl]-1,3,5-triazine-2,4-di-amine].

Authors:  Mayokun J Ayodele; Travis C Green; W A Chathuri V Warsapperuma; Malcolm D E Forbes; Alexis D Ostrowski
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2021-02-26

5.  O2 activation by binuclear Cu sites: noncoupled versus exchange coupled reaction mechanisms.

Authors:  Peng Chen; Edward I Solomon
Journal:  Proc Natl Acad Sci U S A       Date:  2004-08-30       Impact factor: 11.205

6.  Catalytic phenol hydroxylation with dioxygen: extension of the tyrosinase mechanism beyond the protein matrix.

Authors:  Alexander Hoffmann; Cooper Citek; Stephan Binder; Arne Goos; Michael Rübhausen; Oliver Troeppner; Ivana Ivanović-Burmazović; Erik C Wasinger; T Daniel P Stack; Sonja Herres-Pawlis
Journal:  Angew Chem Int Ed Engl       Date:  2013-04-22       Impact factor: 15.336

7.  Phenolate hydroxylation in a bis(mu-oxo)dicopper(III) complex: lessons from the guanidine/amine series.

Authors:  Sonja Herres-Pawlis; Pratik Verma; Roxana Haase; Peng Kang; Christopher T Lyons; Erik C Wasinger; Ulrich Flörke; Gerald Henkel; T Daniel P Stack
Journal:  J Am Chem Soc       Date:  2009-01-28       Impact factor: 15.419

8.  Access to a Cu(II)-O-Cu(II) motif: spectroscopic properties, solution structure, and reactivity.

Authors:  Peter Haack; Anne Kärgel; Claudio Greco; Jadranka Dokic; Beatrice Braun; Florian F Pfaff; Stefan Mebs; Kallol Ray; Christian Limberg
Journal:  J Am Chem Soc       Date:  2013-10-17       Impact factor: 15.419

9.  Geometric and electronic structure of [{Cu(MeAN)}2(μ-η2:η2(O2(2-)))]2+ with an unusually long O-O bond: O-O bond weakening vs activation for reductive cleavage.

Authors:  Ga Young Park; Munzarin F Qayyum; Julia Woertink; Keith O Hodgson; Britt Hedman; Amy A Narducci Sarjeant; Edward I Solomon; Kenneth D Karlin
Journal:  J Am Chem Soc       Date:  2012-05-09       Impact factor: 15.419

10.  Biomimetic modeling of copper complexes: a study of enantioselective catalytic oxidation on d-(+)-catechin and L-( - )-epicatechin with copper complexes.

Authors:  Francesco G Mutti; Roberta Pievo; Maila Sgobba; Michele Gullotti; Laura Santagostini
Journal:  Bioinorg Chem Appl       Date:  2008       Impact factor: 7.778
  10 in total

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