Literature DB >> 10671250

Evidence for an Equilibrium between an N-heterocyclic Carbene and Its Dimer in Solution.

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Abstract

Evidence for the Wanzlick equilibrium between carbene 1 and dibenzotetraazafulvalene (1)(2) at ambient temperature has been found (see scheme). Enetetramines of type (1)(2) can also be cleaved by coordinatively unsaturated transition metal compounds to form dicarbene complexes.

Entities:  

Year:  2000        PMID： 10671250     DOI： 10.1002/(sici)1521-3773(20000204)39:3<541::aid-anie541>3.0.co;2-b

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  6 in total

Review 1.  Stable cyclic carbenes and related species beyond diaminocarbenes.

Authors:  Mohand Melaimi; Michèle Soleilhavoup; Guy Bertrand
Journal:  Angew Chem Int Ed Engl       Date:  2010-11-15       Impact factor: 15.336

2.  Can a Wanzlick-like equilibrium exist between dicoordinate borylenes and diborenes?

Authors:  Felipe Fantuzzi; Yinchun Jiao; Rian D Dewhurst; Frank Weinhold; Holger Braunschweig; Bernd Engels
Journal:  Chem Sci       Date:  2022-03-04       Impact factor: 9.969

3.  Rearrangement of biaryl monoaminocarbenes via concerted asynchronous insertion into aromatic C-H bonds.

Authors:  Joan Vignolle; Matthew Asay; Karinne Miqueu; Didier Bourissou; Guy Bertrand
Journal:  Org Lett       Date:  2008-09-03       Impact factor: 6.005

4.  NHC-Based Self-Assembled Monolayers on Solid Gold Substrates.

Authors:  Tobias Weidner; Joe E Baio; Alexander Mundstock; Christoph Große; Silvia Karthäuser; Clemens Bruhn; Ulrich Siemeling
Journal:  Aust J Chem       Date:  2011-08-19       Impact factor: 1.321

5.  A comparison of diamino- and diamidocarbenes toward dimerization.

Authors:  Chin-Hung Lai
Journal:  J Mol Model       Date:  2013-08-06       Impact factor: 1.810

6.  Synthesis of N-Heterocyclic Carbenes and Their Complexes by Chloronium Ion Abstraction from 2-Chloroazolium Salts Using Electron-Rich Phosphines.

Authors:  Matthias D Böhme; Tobias Eder; Maike B Röthel; Patrick D Dutschke; Lukas F B Wilm; F Ekkehardt Hahn; Fabian Dielmann
Journal:  Angew Chem Int Ed Engl       Date:  2022-05-17       Impact factor: 16.823
  6 in total

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