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Literature DB >> 10671241

Al(30): A Giant Aluminum Polycation.

Abstract

Simple hydrothermal treatment of the well-known aluminum polycation varepsilon-Al(13) produces the novel Al(30) structure (see picture), the largest polycation yet observed. Its characterization, by X-ray diffraction and NMR spectroscopy, also solved previously unassigned signals in (27)Al NMR spectra of other Al - O species.

Entities: Chemical

Year: 2000 PMID： 10671241 DOI： 10.1002/(sici)1521-3773(20000204)39:3<511::aid-anie511>3.0.co;2-n

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

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Cited

8 in total

1. Dissolution of insulating oxide materials at the molecular scale.

Authors: C André Ohlin; Eric M Villa; James R Rustad; William H Casey
Journal: Nat Mater Date: 2009-11-17 Impact factor: 43.841

2. Energetics of Al₁₃ Keggin cluster compounds.

Authors: Christopher R Armstrong; William H Casey; Alexandra Navrotsky
Journal: Proc Natl Acad Sci U S A Date: 2011-08-18 Impact factor: 11.205

3. Electrolytic synthesis of aqueous aluminum nanoclusters and in situ characterization by femtosecond Raman spectroscopy and computations.

Authors: Wei Wang; Weimin Liu; I-Ya Chang; Lindsay A Wills; Lev N Zakharov; Shannon W Boettcher; Paul Ha-Yeon Cheong; Chong Fang; Douglas A Keszler
Journal: Proc Natl Acad Sci U S A Date: 2013-10-28 Impact factor: 11.205

Al(30): A Giant Aluminum Polycation.

1. Dissolution of insulating oxide materials at the molecular scale.

2. Energetics of Al₁₃ Keggin cluster compounds.

3. Electrolytic synthesis of aqueous aluminum nanoclusters and in situ characterization by femtosecond Raman spectroscopy and computations.

4. High-poly-aluminum chloride sulfate coagulants and their coagulation performances for removal of humic acid.

5. Cyclic growth of hierarchical structures in the aluminum-silicate system.

6. Thermal Emission of Alkali Metal Ions from Al₃₀-Pillared Montmorillonite Studied by Mass Spectrometric Method.

7. Chemical trigger toward phase separation in the aqueous Al(III) system revealed.

8. ²⁷Al NMR Study of the pH Dependent Hydrolysis Products of Al₂(SO₄)₃ in Different Physiological Media.