Literature DB >> 10649396

An EPR Investigation of the Kinetics of Inclusion of a Persistent Radical in Water-Soluble Calix

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Abstract

Distinct EPR signals are observed for the free and included species for the inclusion of the neutral benzyl tert-butyl nitroxide probe into a calix[4]arene host in water (shown schematically). Computer simulation of the EPR spectra recorded at various temperature enabled direct determination of the activation and kinetic parameters for this inclusion process.

Entities:  

Year:  2000        PMID: 10649396     DOI: 10.1002/(sici)1521-3773(20000103)39:1<263::aid-anie263>3.0.co;2-f

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN: 1433-7851            Impact factor:   15.336


  1 in total

1.  EPR Spectroscopy: A Powerful Tool to Analyze Supramolecular Host•Guest Complexes of Stable Radicals with Cucurbiturils.

Authors:  Fengbo Liu; Hakim Karoui; Antal Rockenbauer; Simin Liu; Olivier Ouari; David Bardelang
Journal:  Molecules       Date:  2020-02-11       Impact factor: 4.411

  1 in total

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