Literature DB >> 10649391

Improved Electrochemistry in Low-Polarity Media Using Tetrakis(pentafluorophenyl)borate Salts as Supporting Electrolytes.

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Abstract

The noncoordinating anion [B(C(6)F(5))(4)](-) solubilizes cations and polycations, allowing the generation and study of such systems in low-dielectric media. Thus, when [NBu(4)][B(C(6)F(5))(4)] is used as a supporting electrolyte, cyclic voltammetry is possible in aliphatic ethers and other solvents of very low polarity.

Entities:  

Year:  2000        PMID： 10649391     DOI： 10.1002/(sici)1521-3773(20000103)39:1<248::aid-anie248>3.0.co;2-3

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  4 in total

1.  High-spin ground states via electron delocalization in mixed-valence imidazolate-bridged divanadium complexes.

Authors:  Bettina Bechlars; Deanna M D'Alessandro; David M Jenkins; Anthony T Iavarone; Starla D Glover; Clifford P Kubiak; Jeffrey R Long
Journal:  Nat Chem       Date:  2010-03-21       Impact factor: 24.427

2.  Maximizing Electron Exchange in a [Fe3] Cluster.

Authors:  Raúl Hernández Sánchez; Amymarie K Bartholomew; Tamara M Powers; Gabriel Ménard; Theodore A Betley
Journal:  J Am Chem Soc       Date:  2016-02-09       Impact factor: 15.419

3.  Ligand Field Strength Mediates Electron Delocalization in Octahedral [((H)L)2Fe6(L')m](n+) Clusters.

Authors:  Raúl Hernández Sánchez; Shao-Liang Zheng; Theodore A Betley
Journal:  J Am Chem Soc       Date:  2015-08-21       Impact factor: 15.419

4.  Electronic Coupling in 1,2,3-Triazole Bridged Ferrocenes and Its Impact on Reactive Oxygen Species Generation and Deleterious Activity in Cancer Cells.

Authors:  Przemysław Biegański; Eduard Kovalski; Noel Israel; Evgenia Dmitrieva; Damian Trzybiński; Krzysztof Woźniak; Valerije Vrček; Martina Godel; Chiara Riganti; Joanna Kopecka; Heinrich Lang; Konrad Kowalski
Journal:  Inorg Chem       Date:  2022-06-14       Impact factor: 5.436
  4 in total

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