| Literature DB >> 10649326 |
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Abstract
The various reactive sites in the 16 e complex 1 invite addition reactions with alkynes. After addition of 2 to one of the Rh-S bonds, B-H activation takes place which finally leads to the complex 3, in which a B(3)/B(6)-disubstituted o-carborane cage is present for the first time.Entities:
Year: 1999 PMID： 10649326 DOI： 10.1002/(sici)1521-3773(19991216)38:24<3689::aid-anie3689>3.3.co;2-k
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336