Correcting tritium concentrations in water vapor monitored with silica gel.

A correction is needed to calculate the activity concentration of airborne tritium oxide when dried silica gel is used as the collector. A tracer study using tritiated water with silica gel showed that the concentration of tritium in desorbed water is lower than that in adsorbed water by a fraction that increases with the amount of adsorbed water. The hypothesis was tested that adsorbed tritiated water is diluted by isotopic exchange with both non-tritiated water and hydroxyl groups within the silica gel matrix. The extent of dilution was measured from 4% to 14% adsorbed water, which is typical of moisture on field collectors for monitoring airborne tritium oxide. For this range of percent adsorbed water, the inferred percent exchangeable water in the silica gel under study was 6.3 +/- 0.1%. This value compares to the silica gel weight loss of 5.3% after heating to 1,050 degrees C. An explanation of the difference between 6.3% and 5.3% is proposed. The contribution of the HTO/H2O vapor pressure isotope effect was considered in calculating isotopic exchange. A curve is presented for correcting the measured tritium concentration in the distillate from the silica gel as a function of the amount of adsorbed water. The tritium tracer procedure is recommended for determining the percent exchangeable water in other silica gels to correct tritium measurements of water vapor collected by them.