| Literature DB >> 10602238 |
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Abstract
Dimethyl sulfoxide templates the assembly of 1,2-bis(chloromercurio)tetrafluorobenzene (1) into an internally Lewis acidic microporous solid of composition 1 small middle dot(DMSO)(3) (2). The channels of 2 contain both chelated and solvate DMSO molecules (omitted in the drawing for clarity), which can be partly exchanged with water molecules. The hydration-dehydration of the resulting compound is reversible.Entities:
Year: 1999 PMID： 10602238 DOI： 10.1002/(sici)1521-3773(19991203)38:23<3547::aid-anie3547>3.0.co;2-p
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336