| Literature DB >> 10602198 |
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Abstract
Unexpected stability is observed for the palladacycloheptane rac-2, which is obtained as major product and single diastereomer from the cyclization of 1 and Pd(0). Up to a temperature of 50 degrees C 2 shows neither reductive elimination nor intramolecular insertion of another olefin.Entities:
Year: 1999 PMID： 10602198 DOI： 10.1002/(sici)1521-3773(19991115)38:22<3370::aid-anie3370>3.0.co;2-x
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336