Literature DB >> 10602183

Rhodium-Catalyzed Formation of Phosphorus-Boron Bonds: Synthesis of the First High Molecular Weight Poly(phosphinoborane).

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Abstract

An inorganic analogue of polystyrene, poly(phenylphosphinoborane) represents the first high molecular weight, well-characterized polymer with a backbone of alternating phosphorus and boron atoms. It is accessible by metal-catalyzed "dehydrocoupling" of a primary phosphane-borane adduct (see scheme).

Entities:  

Year:  1999        PMID： 10602183     DOI： 10.1002/(sici)1521-3773(19991115)38:22<3321::aid-anie3321>3.0.co;2-0

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  5 in total

1.  Effect of the phosphine steric and electronic profile on the Rh-promoted dehydrocoupling of phosphine-boranes.

Authors:  Thomas N Hooper; Miguel A Huertos; Titel Jurca; Sebastian D Pike; Andrew S Weller; Ian Manners
Journal:  Inorg Chem       Date:  2014-03-11       Impact factor: 5.165

2.  Metal-Free Addition/Head-to-Tail Polymerization of Transient Phosphinoboranes, RPH-BH2: A Route to Poly(alkylphosphinoboranes).

Authors:  Christian Marquardt; Titel Jurca; Karl-Christian Schwan; Andreas Stauber; Alexander V Virovets; George R Whittell; Ian Manners; Manfred Scheer
Journal:  Angew Chem Int Ed Engl       Date:  2015-10-02       Impact factor: 15.336

3.  Metal-free dehydropolymerisation of phosphine-boranes using cyclic (alkyl)(amino)carbenes as hydrogen acceptors.

Authors:  Nicola L Oldroyd; Saurabh S Chitnis; Vincent T Annibale; Marius I Arz; Hazel A Sparkes; Ian Manners
Journal:  Nat Commun       Date:  2019-03-26       Impact factor: 14.919

4.  Calix[4]pyrrolato Aluminate Catalyzes the Dehydrocoupling of Phenylphosphine Borane to High Molar Weight Polymers.

Authors:  Florian Schön; Lukas M Sigmund; Friederike Schneider; Deborah Hartmann; Matthew A Wiebe; Ian Manners; Lutz Greb
Journal:  Angew Chem Int Ed Engl       Date:  2022-03-29       Impact factor: 16.823

5.  Dehydrocoupling of phosphine-boranes using the [RhCp*Me(PMe3)(CH2Cl2)][BArF4] precatalyst: stoichiometric and catalytic studies.

Authors:  Thomas N Hooper; Andrew S Weller; Nicholas A Beattie; Stuart A Macgregor
Journal:  Chem Sci       Date:  2015-12-21       Impact factor: 9.825
  5 in total

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