| Literature DB >> 10556900 |
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Abstract
A "CO-like matrix", showing coordination analogous to that of carbonyl groups, is provided by silacalix[4]phosphinine macrocycles. Reaction with Au(I) leads to the first gold(I) complexes of macrocycles, which can be reduced with sodium or potassium to the paramagnetic gold(0) complexes (an example is shown), as evidenced by cyclic voltammetry and EPR spectroscopy.Entities:
Year: 1999 PMID： 10556900 DOI： 10.1002/(sici)1521-3773(19991102)38:21<3194::aid-anie3194>3.0.co;2-o
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336