Literature DB >> 10556894

Carbon Monoxide and Cyanide Ligands in a Classical Organometallic Complex Model for Fe-Only Hydrogenase.

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Abstract

The Fe(I) organometallic complex [(µ-SCH(2)CH(2)CH(2)S)Fe(2)(CO)(6)] provides a structural model for the cyano-carbonyl diiron site of Fe-only hydrogenase as characterized by X-ray crystallography (the picture shows the structure (black) of the model overlaid with that of the Fe-Fe dimetallic site in the hydrogenase isolated from Desulfovibrio desulfuricans). Cyanide substitution of CO occurs readily and provides spectroscopic references for the active site.

Entities:  

Year:  1999        PMID： 10556894

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  33 in total

1.  Better than platinum? Fuel cells energized by enzymes.

Authors:  Jesse W Tye; Michael B Hall; Marcetta Y Darensbourg
Journal:  Proc Natl Acad Sci U S A       Date:  2005-11-14       Impact factor: 11.205

Review 2.  Hydrogenase Enzymes and Their Synthetic Models: The Role of Metal Hydrides.

Authors:  David Schilter; James M Camara; Mioy T Huynh; Sharon Hammes-Schiffer; Thomas B Rauchfuss
Journal:  Chem Rev       Date:  2016-06-29       Impact factor: 60.622

3.  Chelate control of diiron(I) dithiolates relevant to the [Fe-Fe]- hydrogenase active site.

Authors:  Aaron K Justice; Giuseppe Zampella; Luca De Gioia; Thomas B Rauchfuss; Jarl Ivar van der Vlugt; Scott R Wilson
Journal:  Inorg Chem       Date:  2007-02-06       Impact factor: 5.165

4.  Ultrafast Photodynamics of Cyano-Functionalized [FeFe] Hydrogenase Model Compounds.

Authors:  Christopher J Stromberg; Edwin J Heilweil
Journal:  J Phys Chem A       Date:  2018-04-18       Impact factor: 2.781

5.  [Fe-Fe]-hydrogenase Reactivated by Residue Mutations as Bridging Carbonyl Rearranges: A QM/MM Study.

Authors:  Stefan Motiu; Valentin Gogonea
Journal:  Int J Quantum Chem       Date:  2010-11-15       Impact factor: 2.444

6.  Biomimetic assembly and activation of [FeFe]-hydrogenases.

Authors:  A Adamska; C Lambertz; T R Simmons; G Berggren; J Esselborn; M Atta; S Gambarelli; J M Mouesca; E Reijerse; W Lubitz; T Happe; V Artero; M Fontecave
Journal:  Nature       Date:  2013-06-26       Impact factor: 49.962

7.  Residue Mutations in [Fe-Fe]-hydrogenase Impedes O(2) Binding: A QM/MM Investigation.

Authors:  Daniela Dogaru; Stefan Motiu; Valentin Gogonea
Journal:  Int J Quantum Chem       Date:  2009-10-22       Impact factor: 2.444

8.  The organometallic active site of [Fe]hydrogenase: models and entatic states.

Authors:  Marcetta Y Darensbourg; Erica J Lyon; Xuan Zhao; Irene P Georgakaki
Journal:  Proc Natl Acad Sci U S A       Date:  2003-03-17       Impact factor: 11.205

9.  Diiron dithiolato carbonyls related to the H(ox)CO state of [FeFe]-hydrogenase.

Authors:  Aaron K Justice; Mark J Nilges; Thomas B Rauchfuss; Scott R Wilson; Luca De Gioia; Giuseppe Zampella
Journal:  J Am Chem Soc       Date:  2008-03-15       Impact factor: 15.419

10.  Borane-protected cyanides as surrogates of H-bonded cyanides in [FeFe]-hydrogenase active site models.

Authors:  Brian C Manor; Mark R Ringenberg; Thomas B Rauchfuss
Journal:  Inorg Chem       Date:  2014-07-03       Impact factor: 5.165
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