| Literature DB >> 1054826 |
R R Gaughan, D F Shriver, L J Boucher.
Abstract
Unique resonance Raman spectra were obtained when manganese(III) tetraphenylporphin halides in noncoordinating solvents were illuminated by laser frequencies around 500 nm. Of particular interest is the observation of a feature that is sensitive to the nature of the axial ligand. This feature disappears when the coordinating solvent pyridine is employed, and it, therefore, appears to be diagnostic of the manganese coordination number.Entities:
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Year: 1975 PMID: 1054826 PMCID: PMC432325 DOI: 10.1073/pnas.72.2.433
Source DB: PubMed Journal: Proc Natl Acad Sci U S A ISSN: 0027-8424 Impact factor: 11.205