Literature DB >> 10535910

Pressure-enhanced ortho-para conversion in solid hydrogen up to 58 GPa.

J H Eggert1, E Karmon, R J Hemley, A Mao, A F Goncharov.   

Abstract

We measured the ortho-para conversion rate in solid hydrogen by using Raman scattering in a diamond-anvil cell, extending previous measurements by a factor of 60 in pressure. We confirm previous experiments that suggested a decrease in the conversion rate above about 0.5 GPa. We observe a distinct minimum at 3 GPa followed by a drastic increase in the conversion rate to our maximum pressure of 58 GPa. This pressure enhancement of conversion is not predicted by previous theoretical treatments and must be due to a new conversion pathway.

Entities:  

Year:  1999        PMID: 10535910      PMCID: PMC22905          DOI: 10.1073/pnas.96.22.12269

Source DB:  PubMed          Journal:  Proc Natl Acad Sci U S A        ISSN: 0027-8424            Impact factor:   11.205


  4 in total

1.  Crystal structure of molecular hydrogen at high pressure.

Authors: 
Journal:  Phys Rev Lett       Date:  1995-02-27       Impact factor: 9.161

2.  Infrared Properties of Ortho and Mixed Crystals of Solid Deuterium at Megabar Pressures and the Question of Metallization in the Hydrogens.

Authors: 
Journal:  Phys Rev Lett       Date:  1995-05-15       Impact factor: 9.161

3.  Invariant points and phase transitions in deuterium at megabar pressures.

Authors: 
Journal:  Phys Rev Lett       Date:  1995-09-25       Impact factor: 9.161

4.  Raman excitations and orientational ordering in deuterium at high pressure.

Authors: 
Journal:  Phys Rev B Condens Matter       Date:  1996-12-01
  4 in total

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