| Literature DB >> 10508351 |
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Abstract
Highly strained methylenephosphiranes are formed in the reaction of the new electrophilic phosphinidene complex [iPr(2)N-P=Fe(CO)(4)] with allenes. Remarkably, reaction with diallenes at 0 degrees C also leads to a phosphirane, which rearranges upon warming to room temperature to a bis-isopropylidenephospholene (see scheme).Entities:
Year: 1999 PMID： 10508351 DOI： 10.1002/(sici)1521-3773(19990903)38:17<2596::aid-anie2596>3.0.co;2-i
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336