Literature DB >> 10425500

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Abstract

The long-postulated reactive intermediates of polar fluoride-inititated trifluoromethylations with Me(3)SiCF(3) (see scheme) were identified by NMR spectroscopy as [Me(3)Si(CF(3))F](-) and [Me(3)Si(CF(3))(2)](-)(.)

Entities:  

Year:  1999        PMID: 10425500     DOI: 10.1002/(sici)1521-3773(19990802)38:15<2252::aid-anie2252>3.0.co;2-z

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN: 1433-7851            Impact factor:   15.336


  4 in total

1.  Copper-mediated difluoromethylation of aryl and vinyl iodides.

Authors:  Patrick S Fier; John F Hartwig
Journal:  J Am Chem Soc       Date:  2012-03-14       Impact factor: 15.419

2.  Trifluoromethylation of [AuF3 (SIMes)]: Preparation and Characterization of [Au(CF3 )x F3-x (SIMes)] (x=1-3) Complexes.

Authors:  Marlon Winter; Niklas Limberg; Mathias A Ellwanger; Alberto Pérez-Bitrián; Karsten Sonnenberg; Simon Steinhauer; Sebastian Riedel
Journal:  Chemistry       Date:  2020-10-27       Impact factor: 5.236

3.  In Situ Studies of Arylboronic Acids/Esters and R3SiCF3 Reagents: Kinetics, Speciation, and Dysfunction at the Carbanion-Ate Interface.

Authors:  Andrés García-Domínguez; Andrew G Leach; Guy C Lloyd-Jones
Journal:  Acc Chem Res       Date:  2022-04-18       Impact factor: 24.466

4.  Oxidative Additions of C-F Bonds to the Silanide Anion [Si(C2 F5 )3 ].

Authors:  Natalia Tiessen; Mira Keßler; Beate Neumann; Hans-Georg Stammler; Berthold Hoge
Journal:  Angew Chem Int Ed Engl       Date:  2022-02-28       Impact factor: 16.823

  4 in total

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