| Literature DB >> 10425480 |
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Abstract
The right- and left-handed propeller-shaped enantiomers of the eight-coordinate SmI(2) complexes shown can be resolved by crystallization from dimethoxyethane (dme) at ambient temperature. Apart from representing a new type of chiral metal complex, such enantiomers are potential reagents for enantioselective reductions.Entities:
Year: 1999 PMID： 10425480
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336